Strain Hardening and Highly Resilient Hydrogels Crosslinked by Chain-Extended Reactive Pseudo-Polyrotaxane
作者：Yulin Cui, Mei Tan, Aidi Zhu and Mingyu Guo *
關(guān)鍵字：Strain Hardening and Highly Resilient Hydrogels
論文來源：期刊
具體來源：RSC Adv. 2014, 4, 56791-56797.
發(fā)表時間：2014年
Strain hardening and high resilience are two unique mechanical characteristics of many soft biological hydrogels. However, these properties, especially the strain hardening behaviour, are generally not seen in synthetic polymer hydrogels. Here, hydrogels are prepared by free-radical copolymerization of acrylamide and chain-extended vinyl-modified pseudo-polyrotaxane, which acts as a multifunctional crosslinker. The reactive pseudo-polyrotaxane is based on a b-cyclodextrin monomer and amineterminated PEG–PPG–PEG (Pluronic F127). The obtained hydrogels can be stretched from 10 to more than 26 times their original length before breaking and withstand a compression strain of 95% and even 98% without fracture. Tensile stretching tests show obvious strain hardening behaviours in high
stretching and compression deformation regimes. The strain hardening behaviour in stretching deformation is considered to be the orientation and aggregation of the movable crosslinkers along the axial polymer backbone. Moreover, the formation of a second supramolecular network due to the chainextension effect may also be responsible for it. Highly resilient behaviours with almost no hysteresis and residual strains are also observed even with a maximum strain of 12 because of the inherent freely movable character of the crosslinkers.