One-pot synthesis of hyperbranched polyethylenes tethered with polymerizable methacryloyl groups via selective ethylene copolymerization with heterobifunctional comonomers by chain walking Pd-diimine catalysis
writer：J. Wang, K. Zhang, Z. Ye*
keywords：無(wú)
source：期刊
specific source：Macromolecules
Issue time：2008年
We synthesized hyperbranched polyethylenes tethered with polymerizable methacryloyl groups, utilizing the unique selective copolymerization of ethylene with two heterobifunctional
comonomers, AEM and DMPM. These functionalized hyperbranched polymers exhibit low glass transition temperature and low melt viscosity and have great potential for applications like inkjet printable UV-curable macro-cross-linker.