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A facile one-step synthesis to cross-linked polymeric nanoparticles as highly active and selective catalysts for cycloaddition of CO2 to epoxides
作者:Yubing Xiong, Hong Wang, Rongmin Wang,Yunfeng Yanb Bo Zheng,Yunpu Wang
關(guān)鍵字:Aerobic oxidation; Polymer-bound Schiff base ternary;complexes; Linear aliphatic olefins; Epoxidation
論文來源:期刊
具體來源:Chem. Commun., 2010, 46, 3399–3401 | 3399
發(fā)表時間:2010年

A very convenient one-step synthesis to cross-linked polymeric nanoparticles by conventional radical copolymerization without the addition of stabilizers or surfactants was explored. Moreover, these nanoparticles exhibited excellent stability, activity and selectivity in the cycloaddition reaction of CO2 to epoxides and
could be separated from the products easily and reused.