Enhanced proton conductivity of poly (arylene ether ketone sulfone) containing uneven sulfonic acid side chains by incorporating imidazole functionalized metal-organic framework
作者：Xuan Chen, Jingmei Xu
關(guān)鍵字：sulfonated poly(arylene ether ketone sulfone)s，MOFs
論文來(lái)源：期刊
具體來(lái)源：International Journal of Hydrogen Energy
發(fā)表時(shí)間：2021年
In this study, the side-chain type hybrid proton exchange membranes which based on metal-organic frameworks (MOFs) and organic matrix of sulfonated poly (arylene ether ketone sulfone) containing both long and short sulfonic acid side chains (C-SPAEKS-DBS) were prepared. MOF-801 was used as a template and then imidazole was encapsulated into MOF-801 as additional proton carriers. In imidazole -MOF-801, imidazole was used as a functional group to coordinate with the zirconium metal site of the functional group. Imidazole-MOF-801 and hybrid membranes were characterized by XRD, 1H NMR and FT-IR. These hybrid membranes exhibited excellent proton conductivity and good thermal stability.