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Electrochemical fabrication of nanoporous polypyrrole thin films
作者:Mei Li, Jinying Yuan *, Gaoquan Shi *
關(guān)鍵字:Polypyrrole; Conductivity; Nanostructures; Raman scattering
論文來源:期刊
具體來源:Thin Solid Films. 2008, 516:3836-3840
發(fā)表時(shí)間:2008年

Polypyrrole thin films with pores in nanometer scale were synthesized by direct electrochemical oxidation of pyrrole in a mixed electrolyte of isopropyl alcohol, boron trifluoride diethyl etherate, sodium dodecylsulfonate and poly(ethylene glycol) using well-aligned ZnO nanowires arrays as templates. The thin films exhibit high conductivity of ca. σrt ∼20.5 s/cm and can be driven to bend during redox processes in 1.0 M lithium perchlorate aqueous solution. The movement rate of an actuator based on this nanoporous film was measured to be over 90°/s at a driving potential
of 0.8 V (vs. Ag/AgCl).