Aqueous RAFT Polymerization of Imidazolium-Type Ionic Liquid Monomers: En Route to Poly(ionic liquid)-Based Nanoparticles through RAFT Polymerization-Induced Self-Assembly
作者：B. Zhang, X. Yan, P. Alcouffe, A. Charlot, E. Fleury, and J. Bernard.
關(guān)鍵字：Aqueous RAFT Polymerization，Imidazolium-Type Ionic Liquid，RAFT Polymerization-Induced Self-Assembly
論文來(lái)源：期刊
具體來(lái)源：ACS Macro Letters
發(fā)表時(shí)間：2015年
The synthesis by aqueous RAFT polymerization of hydrophilic narrowly dispersed imidazolium-based poly(ionic liquid)s (? typically below 1.20) is reported. Full monomer conversion is achieved within hours and high endgroup fidelity of the living end groups affords the preparation
of well-defined block copolymers. The resulting poly(ionic liquid) macroRAFT agents are finally exploited to polymerize 2-vinylpyridine in water and generate PIL-based nanoparticles of various morphologies (spheres, vesicles, or worms) in a onepot surfactant-free process.