[Chem. Res. Chin. Univ.] Functionalized Polyphosphoester via Living Ring-opening Polymerization and Photochemical Thiol-ene Click Reaction
作者：Wang Ying; Wang Qiliao; Hou Liman; Zhou Mingdong; Dong Dewen; Zhang Ning
關(guān)鍵字：Click Reaction，Polyphosphoester，Ring-opening Polymerization
論文來源：期刊
具體來源：Chem. Res. Chin. Univ.
發(fā)表時間：2019年
Poly(ethylene phosphonate) was synthesized via the living ring-opening polymerization of cyclic phosphonate monomer catalyzed by organocatalyst. The pendant vinyl functionalities were employed to perform the photochemical click reactions with thiols. We demonstrated that both small thiol molecules and macromolecular thiols could be efficiently coupled into the PPE side chains, enabling the rapid and efficient functionalization of polyphosphoesters( PPE).