Effect of Reactive Emulsifier on the Emulsion Polymerization of Acrylate with Hydroxyl Monomer
作者：Fa-Ai Zhang, Cai-Li Yu, Chun Wei
關(guān)鍵字：acrylate emulsion, polymerization, reactive emulsifier, hydroxyl monomer
論文來源：會議
具體來源：The Proceeding of 2005 International Conference on Advanced Fibers and Polymer Materials(ICAFPM 2005
發(fā)表時(shí)間：2005年
The emulsion copolymerization composing of
butyl acrylate, methyl methacrylate, hydroxylethyl methacrylate and acrylic
acid using reactive emulsifier R208 and AOPS-1 was studied at different emulsifier
type, level of emulsifier and initiator, reactive temperature with
regard to monomer
conversion. The particle size and distribution of the emulsion were
also investigated.
It indicated that reactive emulsifier decreased the polymerization rate. The polymerization rate increased with the
increase of reaction temperature, level of initiator, and amount of emulsifier.
The particle size also increased with the increase of reaction temperature and
level of initiator. Small amount of reactive emulsifier increased the particle
size.