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High gas storage capacities and stepwise adsorption in a UiO type metal-organic framework incorporating Lewis basic bipyridyl sites
作者:Liangjun Li, Sifu Tang, Chao Wang, Xiaoxia Lv, Min Jiang, Huaizhi Wu, Xuebo Zhao
關(guān)鍵字:UiO type metal-organic framework
論文來源:期刊
具體來源:ChemComm,2014,50, 2304-2307
發(fā)表時間:2014年
A UiO type MOF with Lewis basic bipyridyl sites was synthesized and structurally characterized. After being activated by Soxhlet-extraction, this MOF exhibits high storage capacities for H2, CH4and CO2, and shows unusual stepwise adsorption for liquid CO2 and solvents, indicating a sequential filling mechanism on different adsorption sites.