Metal nanoparticles supported on WO3 nanosheets for highly selective hydrogenolysis of cellulose to ethylene glycol
作者：Li, NX (Li, Naixu)[ 1 ] ; Zheng, Y (Zheng, Yu)[ 1 ] ; Wei, LF (Wei, Lingfei)[ 1 ] ; Tenga, HC (Tenga
關(guān)鍵字：CATALYTIC CONVERSION; CARBIDE CATALYSTS; CRYSTAL-STRUCTURE; TUNGSTEN CARBIDE; REACTION NETWORK; BIOMASS; CHEMICALS; GLUCOSE; TRANSFORMATION; HYDROGENATION
論文來源：期刊
具體來源：GREEN CHEMISTRY
發(fā)表時(shí)間：2017年
Although the conversion of cellulose to polyols is currently well-developed, the production of the considerably valuable ethylene glycol (EG) is still challenging. Reactions have long relied on the design of suitable catalysts to obtain a high selectivity and yield of EG. Herein, using well-shaped rectangular tungsten trioxide nanosheets as the substrate, we investigated the catalytic performances of various metal supported catalysts for the convertion of cellulose to EG. Results show that Ru/WO3 is more favorable for EG production, with the highest EG yield of 76.3% over the 1% Ru/WO3 nanosheet catalyst. Our characterizations and activity tests suggest that the embedding of Ru nanoparticles onto the WO3 nanosheets produces more W5+ active sites under the same reduction conditions (NaBH4 or H-2), which act as Lewis base sites to promote the glucose retro-aldol condensation reaction. Moreover, the Ru/WO3 catalyst holds a portion of Ru in the form of amorphous RuOx delta+ phases, which could further increase the H+ released into an aqueous solution for cellulose hydrogenolysis. A possible catalytic mechanism for this hydrogenolysis process is accordingly proposed.