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1. ?/span>?/span>?/span>?/span>


?/span>?/span>?/span>?/span>l?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>Q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>U?/span>?/span>?/span>?/span>?/span>?/span>?/span>U?/span>TiO2?/span>U?/span>c?/span>?/span>_?/span>?/span>?/span>?/span>?/span>?/span>l?/span>?/span>?/span>?/span>?/span>Q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>U?/span>?/span>TiO2?/span>_?/span>?/span>?/span>?/span>Q?/span>?/span>?/span>?/span>U?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>/?/span>?/span>?/span>?/span>?/span>Q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>1C?/span>Q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>Q?/span>PFOAQ?/span>?/span>?/span>?/span>CF3(CF2)6COO-?/span>?/span>?/span>q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>U?/span>?/span>TiO2?/span>?/span>Q?/span>?/span>?/span>?/span>?/span>?/span>U?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>NH4 ?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>NH4 ?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>Q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>Q?/span> ?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>NH4 ?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>Q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>


?/span>1 ?/span>?/span>?/span>?/span>/?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>Q?/span>?/span>?/span>TiO2?/span>_?/span>?/span>?/span>?/span>?/span>?/span>


2.?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>


?/span>q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>/?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>/?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>NH4 ?/span>?/span>?/span>?/span>?/span>?/span>Q?/span>?/span>?/span>?/span>?/span>?/span>2?/span>?/span>?/span>Q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>/?/span>?/span>?/span>?/span>Q?/span>q?/span>?/span>?/span>?/span>?/span>?/span>?/span>TiO2?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>-OH?/span>?/span>?/span>q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>Q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>/?/span>?/span>?/span>?/span>?/span>?/span>?/span>l?/span>q?/span>?/span>?/span>?/span>?/span>z?/span>q?/span>?/span>?/span>?/span>q?/span>?/span>?/span>q?/span>?/span>Q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>q?/span>?/span>?/span>?/span>?/span>CF3(CF2)6COO-?/span>l?/span>?/span>?/span>Q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>TiO2?/span>?/span>?/span>CF3(CF2)6COO-Q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>Q?/span>l?/span>?/span>?/span>?/span>?/span>?/span>?/span>/?/span>?/span>?/span>?/span>?/span>?/span>?/span>Q?/span>?/span>2Q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>Q?/span>?/span>3Q?/span>?/span>


?/span>2 ?/span>?/span>?/span>?/span>/?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>/?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>


?/span>3Q?/span>aQ?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span> Q?/span>bQ?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>


3.?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>


?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>l?/span>?/span>?/span>?/span>q?/span>?/span>|?/span>?/span>Q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>q?/span>E?/span>?/span>?/span>?/span>?/span>?/span>?/span>4C?/span>Q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>/?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>-?/span>?/span>?/span>?/span>?/span>q?/span>?/span>?/span>?/span>Q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>/?/span>?/span>?/span>Q?/span>?/span>q?/span>?/span>?/span>?/span>-?/span>?/span>?/span>?/span>?/span>I?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>q?/span>?/span>?/span>?/span>?/span>?/span>Q?/span>?/span>5Q?/span>?/span>l?/span>?/span>?/span>?/span>Q?/span>?/span>?/span>?/span>?/span>?/span>?/span>q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>Q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>99.9%?/span>?/span>?/span>


?/span>4 ?/span>?/span>(a)?/span>?/span>?/span>(b)?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>


?/span>5 ?/span>?/span>?/span>(a)?/span>?/span>?/span>?/span>(b)?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>


4.?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>


TiO2?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>Q?/span>q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>_?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>l?/span>?/span>CO2?/span>H2O?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>Q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>q?/span>E?/span>?/span>?/span>?/span>?/span>U?/span>?/span>?/span>?/span>q?/span>?/span>?/span>?/span>?/span>?/span>Q?/span>?/span>6Q?/span>Q?/span>l?/span>q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>Q?/span>?/span>?/span>?/span>?/span>l?/span>?/span>?/span>(g)?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>Q?/span>l?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>


?/span>6 ?/span>?/span>?/span>?/span>TiO2?/span>?/span>PFOA?/span>?/span>?/span>?/span>U?/span>?/span>?/span>?/span>?/span>

?/span>?/span>?/span>W?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>Q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>q?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>I?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>U?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>?/span>


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https://doi.org/10.1021/acsami.1c08500

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