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[Macromolecules] Synthesis and Stereospecific Polymerization of a Novel Bulky Styrene Derivative
來源:劉東濤教授個人網(wǎng)站 發(fā)布日期:2020-08-02
作者:Rong Wang#, Dongtao Liu#(共同一作), Xiaohong Li, Jie Zhang, Cui Dongmei*, Xinhua Wan*
關鍵字:Stereospecific Polymerization, Bulky Styrene Derivative
論文來源:期刊
發(fā)表時間:2016年

A novel vinylbiphenyl monomer, 2-methoxy-5-phenylstyrene (MOPS), was designed and efficiently synthesized to investigate the stereospecific polymerization of bulky and polar styrenic derivative. Regardless of its large side group and electron-donating o-methoxy substituent, this compound showed a high polymerizability and was readily converted to the corresponding polymers with moderate to high molecular mass through radical, anionic, and coordination polymerizations.


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