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Crystallization and Structural Analysis of Poly(trimethylene terephthalate) Film Studied by Raman Spectroscopy  
Crystallization and Structural Analysis of Poly(trimethylene terephthalate) Film Studied by Raman Spectroscopy
資料類型: PDF文件
關(guān)鍵詞: poly(trimethylene  terephthalate)  crystallization  raman  spectrum  
資料大?。?/td> 101K
所屬學(xué)科: 分子表征
來源: 第六屆亞歐研討會上處理和性能增強聚合物會議文集(2013.6.2-6 武漢)
簡介:
Poly(trimethyleneterephthalate)(PTT)exhibitsexcellenthighbirefringence,luminoustransmittance,resilienceandprocessingpropertieswhichcanbeappliedinopticalcommunications,fiberandthermoplasticengineering.ThemacroscopicpropertiesofsemicrystallinePTT,suchasdegreeofcrystallizationanddevelopmentofthespheruliteshavecloserelationswithitsmicrostructureandspecificmorphologies.Althoughitiswellestablishedreliabletheoriesenablingthepredictionofcrystallizationkinetics,butchanginginstructureandpropertiesduringcoldcrystallizationhasremainedasubjectofspeculationandcontroversy.Inthisstudy,thedynamicprocessofcoldcrystallizationofamorphousPTTwasinvestigatedbyRamanspectrum.Theinformationofeachphaseduringcrystallization,includinginduction,nucleation,nucleusgrowthandsecondarycrystallizationwasrevealedbyRamanspectrum.TheexperimentalresultsindicatedthatthekineticsparametersmeasuredbytheRamanmethodwereingoodagreementwiththoseobtainedbydifferentialscanningcalorimetry(DSC).Inaddition,theRamanmethodwascapableofprovidingmoredetailedinformationaboutmoleculemovementandvariationinfinestructures,suchasmoleculearrangementandorientationfluctuationsofrigidsegmentsinthecourseofglasstransitionandcrystallizationinduction.
作者: C. L. Hu,J. Y. Liu, L. Wang
上傳時間: 2013-07-03 14:40:14
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