砂巖類文物是世界歷史文化遺產(chǎn)的重要組成部分,包括古建筑、石窟寺、石刻雕像和歷史紀(jì)念碑等。由于砂巖本身的特性以及戶外因素的影響,這類文物受溫度、濕度、水、可溶鹽、紫外線等的侵蝕,出現(xiàn)不同程度的劣化。為了保護(hù)這些文物,亟需開發(fā)合適的材料對(duì)其進(jìn)行有效保護(hù),保護(hù)或延緩這些因素造成的侵蝕和破壞。
近期,西安交通大學(xué)和玲/潘愛(ài)釗課題組針對(duì)硅酸鹽材質(zhì)的砂巖基石窟文物風(fēng)化病害的特征及病害形成機(jī)理(砂巖內(nèi)部膠結(jié)質(zhì)流失)等問(wèn)題,將膨潤(rùn)土基抗膨脹水凝膠在砂巖基文物中原位形成以彌補(bǔ)流失的膠結(jié)質(zhì)。首先通過(guò)組分和條件控制調(diào)控了膨潤(rùn)土基水凝膠的原位形成時(shí)間和抗膨脹性,進(jìn)而通過(guò)熒光示蹤技術(shù)研究了膨潤(rùn)土基水凝膠材料在砂巖內(nèi)部的分布,并深入評(píng)估了其在砂巖中的長(zhǎng)效保護(hù)效果,最終研究了其戶外應(yīng)用。該成果在期刊《ACS Applied Materials & Interfaces》上發(fā)表,題為“Insight into a Bentonite-based Hydrogel for the Conservation of Sandstone-based Cultural Heritage: In-situ Formation, Reinforcement Mechanism, and High-Durability Evaluation”的文章(DOI: https://doi.org/10.1021/acsami.2c13122)。
Figure 1. (a) Chemical structure scheme of B-H hydrogel. (b) Schematic illustration of the bentonite-based hydrogel (B-H) formed in-situ in sandstone.

Figure 2. Sandstones (a) after protecting with B-H and (b) traditional hydrogel.

Figure 3. (a) Chemical structure and optical images of the Carbon quantum dots (CQDs) used for fluorescent tracer. Photographs of the appearance (b), cross-sectional surface (b1 and b3) of the sandstones treated by hydrogel-CQDs. Photograph of the appearance (b2) of the fresh sandstones. (c) Morphology and element distribution of Si, C and N elements in the internal grains of the treated sandstone by SEM-mapping. (d) Morphology of the internal grains of the treated sandstone by SEM. (e) Schematic diagram of in-situ formation of hydrogel inside the sandstone.
Figure 4. (a) Acid resistance, (b) salt crystallization cycles in moisture and heat, and (c) freeze-thaw cycles of unprotected and B-H-sandstone. (d) Schematization of the protecting mechanism for freeze-thaw resistance and salt resistance for B-H- sandstone.

Figure 5. Application of bentonite-based hydrogel on actual sandstone-based cultural heritage at Dafo Si. Sampling areas are indicated with red rectangles. Photographs of the sandstones before (a) and after (b) protecting by bentonite-based hydrogel.
全文鏈接:https://pubs.acs.org/doi/full/10.1021/acsami.2c13122
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